128650-74-8

Basic information

• Product Name: 3-Methyl-6-trifluormethyl-1,3-cyclohexadien
• Synonyms: 3-Methyl-6-trifluormethyl-1,3-cyclohexadien
• CAS NO: 128650-74-8
• Molecular Weight: 162.155
• Mol File: 128650-74-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Methyl-6-trifluormethyl-1,3-cyclohexadien(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyl-6-trifluormethyl-1,3-cyclohexadien(128650-74-8)
• EPA Substance Registry System: 3-Methyl-6-trifluormethyl-1,3-cyclohexadien(128650-74-8)

Safety Data

• Hazardous Substances Data: 128650-74-8(Hazardous Substances Data)

Upstream product

• 55642-42-7 bis(trifluoromethyl)tellurium 
• 108-88-3 toluene 

Relevant articles and documents

TRIFLUORMETHYLIERUNGSREAKTIONEN VON Te(CF3)2 MIT HALOGENBENZOLEN UND METHYLBENZOLEN

Substituent effects on yields and regioselectivity of photochemical and thermal trifluoromethylation reactions of Te(CF3)2 with halogen benzenes and methyl benzenes are investigated under comparable conditions.All reactions lead to trifluoromethylated products.The yields of the thermal are always higher than those of the corresponding photochemical reactions.The reactivity of the halobenzenes increases in the series C6H5-F a sidereaction, but H-substitution is the primary reaction pathway.During the reactions with iodobenzene tellurium containing compounds are also formed.The reactions with methyl benzenes show an increase in reactivity in the series hexamethylbenzene mesitylene toluene p-xylene.In all cases only ring substituted products are detected.Reactions with toluene and p-xylene yield tellurium containing compounds as well as addition products.The 19F-n.m.r spectra of the products are given.