129198-58-9Relevant articles and documents
Preparation and Characterisation of , , BF4, and BF4
Parkin, Ivan P.,Woolins, J. Derek
, p. 925 - 930 (2007/10/02)
Reaction of 2Cl2, or SeCl4-Cl, with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia gives complexes of the type (ca. 70percent yield).Reaction of SeCl4 with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia produces in variable yield (ca. 24-74percent).Treatment of or with HBF4 in tetrahydrofuran-benzene produces BF4 or BF4 quantitatively according to 31P n.m.r., i.r., mass spectra, and microanalyses.Proton-exchange reactions reveal increasing basicity in the series ca. , , .