129337-26-4

Basic information

• Product Name: (S)-2-(2,4,6-Trimethyl-phenyl)-2-trimethylsilanyloxy-propionic acid (3aR,4S,7aR)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester
• CAS NO: 129337-26-4
• Molecular Weight: 457.642
• Mol File: 129337-26-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-2-(2,4,6-Trimethyl-phenyl)-2-trimethylsilanyloxy-propionic acid (3aR,4S,7aR)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-(2,4,6-Trimethyl-phenyl)-2-trimethylsilanyloxy-propionic acid (3aR,4S,7aR)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester(129337-26-4)
• EPA Substance Registry System: (S)-2-(2,4,6-Trimethyl-phenyl)-2-trimethylsilanyloxy-propionic acid (3aR,4S,7aR)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester(129337-26-4)

Safety Data

• Hazardous Substances Data: 129337-26-4(Hazardous Substances Data)

Upstream product

• 2633-66-1 2-mesitylmagnesium bromide 
• 136066-63-2 (+/-)-3-<2-methyl-2-(2,4,6-trimethylphenyl)-2-<(trimethylsilyl)oxy>acetoxy>-endo-tricyclo<4.2.1.0^2,5>non-7-ene 
• 136066-62-1 (+/-)-3-<2-hydroxy-2-methyl-2-(2,4,6-trimethylphenyl)acetoxy>-endo-tricyclo<4.2.1.0^2,5>non-7-ene 
• 136066-61-0 3-(2-oxopropionoxy)-endo-tricyclo<4.2.1.0^2,5>non-7-ene 
• 128-53-0 N-Ethylmaleimide 
• 129337-25-3 (+/-)-(E)-1-<2-methyl-2-(2,4,6-trimethylphenyl)-2-<(trimethylsilyl)oxy>acetoxy>-1,3-butadiene 

Relevant articles and documents

Diene-dienophile hydrogen-bonding control of diels-alder reactions with dienes bearing a remote stereogenic center. Amplification of the receptor nature of dienes by conformational tuning leading to high diastereofacial discrimination

The Diels-Alder reactions of 1-(O-methylmandeloxy)butadiene and its analogues, bearing a remote stereogenic center, have been studied to elucidate the stereoselective control elements. Several model dienes (5a-5f) have been designed to enhance the facial