129729-51-7

Basic information

• Product Name: methyl 2,3,4-tri-O-benzyl-6-O-(3’,4’,6’-tri-O-acetyl-2’-N-acetyl-2’-deoxy-β-D-glucopyranosyl)-α-D-glucopyranoside
• CAS NO: 129729-51-7
• Molecular Weight: 793.865
• Mol File: 129729-51-7.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: methyl 2,3,4-tri-O-benzyl-6-O-(3’,4’,6’-tri-O-acetyl-2’-N-acetyl-2’-deoxy-β-D-glucopyranosyl)-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,4-tri-O-benzyl-6-O-(3’,4’,6’-tri-O-acetyl-2’-N-acetyl-2’-deoxy-β-D-glucopyranosyl)-α-D-glucopyranoside(129729-51-7)
• EPA Substance Registry System: methyl 2,3,4-tri-O-benzyl-6-O-(3’,4’,6’-tri-O-acetyl-2’-N-acetyl-2’-deoxy-β-D-glucopyranosyl)-α-D-glucopyranoside(129729-51-7)

Safety Data

• Hazardous Substances Data: 129729-51-7(Hazardous Substances Data)

Upstream product

• 129729-32-4 methyl 2,3,4-tri-O-benzyl-6-O-<3,4,6-tri-O-acetyl-2-(1-cyano-1-p-methoxyphenylmethylamino)-2-deoxy-α-D-glucopyranosyl>-α-D-glucopyranoside 
• 108-24-7 acetic anhydride 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 134160-64-8 4',5'-epoxypentyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside 
• 34212-64-1 methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 129729-50-6 methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-acetyl-2-deoxy-2-p-methoxybenzylideneamino-α-D-glucopyranosyl)-α-D-glucopyranoside 
• 61567-93-9 3,4,6-tri-O-acetyl-2-deoxy-2-(4-methoxybenzyl)imino-α-D-glucopyranosyl bromide 
• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 10294-12-9 2-deoxy-2-acetamido-3,4,6-tri-O-acetyl-D-glucopyranose 
• 5432-46-2 1,3,4,6-tetra-O-acetyl-D-glucosamine hydrochloride 
• 10378-06-0 2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranoso)[1,2-d]-2-oxazoline 
• 3006-60-8 2-acetamido-1,3,4,6-tetra-O-acetyl-2-deoxy-β-D-glucopyranose 
• 27526-42-7 phenyl 2-acetamido-3,4,6-tri-O-acetyl-1,2-di-deoxy-1-thio-β-D-glucopyranoside 
• 187455-96-5 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-[acetyl-(2,2,2-trichloro-ethoxycarbonyl)-amino]-6-ethylsulfanyl-tetrahydro-pyran-4-yl ester 

Downstream Products

• 111462-66-9 β-D-GlcpNAc-(1->6)-α-D-Manp-OMe 

Relevant articles and documents

Dual-participation protecting group solves the anomeric stereocontrol problems in glycosylation reactions

The 2,2-dimethyl-2-(ortho-nitrophenyl)acetyl (DMNPA) group permits, via robust neighboring group participation (NGP) or long distance participation (LDP) effects, the stereocontrolled 1,2-trans, 1,2-cis, as well as β-2,6-dideoxy glycosidic bond generation, while suppressing the undesired orthoester byproduct formation. The robust stereocontrol capability of the DMNPA is due to the dual-participation effect from both the ester functionality and the nitro group, verified by control reactions and DFT calculations and further corroborated by X-ray spectroscopy.

Glycosylation with 2-Acetamido-2-deoxyglycosyl Donors at a Low Temperature: Scope of the Non-Oxazoline Method

A direct construction of 1,2-trans-β-linked 2-acetamido-2-deoxyglycosides was investigated. The 3,4,6-tri-O-benzyl- and 3,4,6-tri-O-acetyl-protected glycosyl diethyl phosphites and 4,6-O-benzylidene-protected galactosyl diethyl phosphite each reacted with

H2so4-silica promoted direct formation of β-glycosides of N-Acetyl glycosylamines under microwave conditions

N-Acetyl glycosamines are important building blocks for the synthesis of biologically active oligosaccharides. This communication describes a simple direct protocol for the synthesis of βglycosides of N-acetyl glycosylamines from easily accessible perO-ac