1298035-48-9Relevant articles and documents
Cu-catalyzed mild and efficient oxidation of THβCs using air: Application in practical total syntheses of perlolyrine and flazin
Zheng, Bo,Trieu, Tien Ha,Meng, Tian-Zhuo,Lu, Xia,Dong, Jing,Zhang, Qiang,Shi, Xiao-Xin
, p. 6834 - 6839 (2018)
A mild, efficient and environmentally benign method for synthesis of aromatic β-carbolines via Cu(ii)-catalyzed oxidation of 1,2,3,4-tetrahydro-β-carbolines (THβCs) was developed, in which air (O2) was used as the clean oxidant. This method has advantages such as environmentally friendliness, mildness, very good tolerance of functional groups, high yielding and easy experiment operation. In addition, this new methodology was successfully applied in the efficient and practical total syntheses of β-carboline alkaloids perlolyrine and flazin.
Intramolecular [4+2]-cycloaddition of 5-amino-substituted oxazoles as an approach toward the left-hand segment of haplophytine
Chughtai, Majid,Eagan, James M.,Padwa, Albert
, p. 215 - 218 (2011/03/20)
The [4+2]-cycloaddition chemistry of several 5-amino-substituted oxazoles has been examined as an approach toward the construction of the left-half segment of the aspidosperma alkaloid haplophytine. Georg Thieme Verlag Stuttgart.