131435-06-8Relevant articles and documents
Stereoselective syntheses of racemic quercitols and bromoquercitols starting from cyclohexa-1,4-diene: Gala-, epi-, muco-, and neo-quercitol
Aydin, G?kay,Savran, Tahir,Akta?, Fatih,Baran, Arif,Balci, Metin
, p. 1511 - 1524 (2013/05/21)
The efficient synthesis of gala-, epi-, neo-, and muco-quercitols and some brominated quercitols starting from cyclohexa-1,4-diene is reported. Treatment of the dibromide, obtained by the addition of bromine to cyclohexa-1,4-diene, with m-chloroperbenzoic
Highly stereoselective and stereospecific syntheses of a variety of quercitols from d-(-)-quinic acid
Shih, Tzenge-Lien,Lin, Ya-Ling,Kuo, Wei-Shen
, p. 1919 - 1924 (2007/10/03)
The highly stereoselective synthesis of (-)-epi-, (-)-allo- and neo-quercitols as well as stereospecific synthesis of (-)-talo- and (+)-gala-quercitols have been achieved. The general strategy is employing dihydroxylation of the isolated double bond of various kinds of protected chiral (1,4,5)-cyclohex-2-ene-triols, which are derived from d-(-)-quinic acid. The choosing of protecting groups from either BBA (butane 2,3-bisacetal) or acetyl groups will result in the various degrees of stereoselectivity of dihydroxylation. On the other hand, the cyclohexylidene acetal moiety is attributed to the stereospecificity during dihydroxylation to afford the request molecules.
Synthesis of the enantiomers of 6-deoxy-myo-inositol 1,3,4,5-Tetrakisphosphate, structural analogues of myo-inositol 1,3,4,5-Tetrakisphosphate
Horne, Graeme,Potter, Barry V. L.
, p. 80 - 87 (2007/10/03)
D-myo-Inositol 1,3,4,5-tetrakisphosphate [Ins(1,3,4,5)P4] is produced rapidly from the established second messenger D-myo-inositol 1,4,5trisphosphate [Ins(1,4,5)P4] in stimulated cells. Despite extensive investigations, in particular