131929-41-4Relevant articles and documents
A Convenient Synthesis of γ-Hydroxy α,β-Unsaturated Sulfones
Trost, Barry M.,Grese, Timothy A.
, p. 3189 - 3192 (2007/10/02)
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A practical route to (E)-γ-hydroxy-αβ-unsaturated phenyl sulfones
Dominguez, Esteban,Carretero, Juan Carlos
, p. 7197 - 7206 (2007/10/02)
Reaction of enolizable aldehydes with p-tolylsulfinylmethyl phenyl sulfone (1) in the presence of piperidine in acetonitrile gave selectively E-γ-hydroxy-αβ-unsaturated phenyl sulfones (2) in good yields. Reaction from enantiomerically pure sulfoxide 1 gave unsaturated sulfones 2 in moderate optical yields (ee= 10-50%).