132150-35-7

Basic information

• Product Name: 3-Ethylsulfanyl-2-methyl-1,3-diphenyl-propan-1-one
• Synonyms: 3-Ethylsulfanyl-2-methyl-1,3-diphenyl-propan-1-one
• CAS NO: 132150-35-7
• Molecular Weight: 284.422
• Mol File: 132150-35-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Ethylsulfanyl-2-methyl-1,3-diphenyl-propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Ethylsulfanyl-2-methyl-1,3-diphenyl-propan-1-one(132150-35-7)
• EPA Substance Registry System: 3-Ethylsulfanyl-2-methyl-1,3-diphenyl-propan-1-one(132150-35-7)

Safety Data

• Hazardous Substances Data: 132150-35-7(Hazardous Substances Data)

Upstream product

• 37471-46-8 1-phenyl-1-trimethylsiloxypropene 
• 59340-48-6 <α-(ethylthio)benzyloxy>trimethylsilane 
• 100-52-7 benzaldehyde 
• 93-55-0 1-phenyl-propan-1-one 
• 75-08-1 ethanethiol 

Relevant articles and documents

Thiol-promoted selective addition of ketones to aldehydes

A simple and efficient thiol-mediated addition of ketones to aromatic and aliphatic aldehydes is reported. This thermodynamically controlled Pummerer/aldol reaction, which can tolerate both moisture and protic functional groups, provides a direct entry to syn-β-thioketones in high chemo- and regioselectivity. Mechanistic studies revealed that selective transformation of the aldehyde to an electrophilic thionium ion species concurrent with the generation of a nucleophilic vinyl sulfide coupling partner from the ketone is imposing cross-coupling over dimerization.