132586-45-9Relevant articles and documents
Topological ferroelectric bistability in a polarization-modulated orthogonal smectic liquid crystal
Zhu, Chenhui,Shao, Renfan,Reddy, R. Amaranatha,Chen, Dong,Shen, Yongqiang,Gong, Tao,Glaser, Matthew A.,Korblova, Eva,Rudquist, Per,MacLennan, Joseph E.,Walba, David M.,Clark, Noel A.
, p. 9681 - 9687 (2012/07/14)
We report a bent-core liquid crystal (LC) compound exhibiting two fluid smectic phases in which two-dimensional, polar, orthorhombic layers order into three-dimensional ferroelectric states. The lower-temperature phase has a uniform polarization field which responds in an analog fashion to applied electric field. The higher-temperature phase is a new smectic state with periodic undulation of the polarization, structurally modulated layers, and a bistable response to applied electric field which originates in the periodically splay-modulated bulk of the LC rather than by surface stabilization at the cell boundaries.