133389-19-2

Basic information

• Product Name: 2-(3-Trifluoromethyl-phenyl)-benzothiazole
• Synonyms: 2-(3-Trifluoromethyl-phenyl)-benzothiazole
• CAS NO: 133389-19-2
• Molecular Formula: C₁₄H₈F₃NS
• Molecular Weight: 0
• Mol File: 133389-19-2.mol
• Article Data: 24

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(3-Trifluoromethyl-phenyl)-benzothiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-Trifluoromethyl-phenyl)-benzothiazole(133389-19-2)
• EPA Substance Registry System: 2-(3-Trifluoromethyl-phenyl)-benzothiazole(133389-19-2)

Safety Data

• Hazardous Substances Data: 133389-19-2(Hazardous Substances Data)

Usage

Structure

Benzothiazole derivative with a trifluoromethyl-phenyl group attached to the benzene ring

Potential use

Fluorescent dye

Promising results

In chemical and biological applications

Trifluoromethyl group

Enhances chemical and biological properties of molecules

Interest for further research

Due to its potential industrial applications

Upstream product

• 2251-65-2 3-(Trifluoromethyl)benzoyl chloride 
• 137-07-5 2-amino-benzenethiol 
• 368-77-4 3-trifluoromethylbenzonitrile 
• 95-16-9 1,3-Benzothiazole 
• 401-81-0 m-trifluoromethylphenyl iodide 
• 1423-26-3 (meta-(trifluoromethyl)phenyl)boronic acid 
• 349-76-8 3'-(trifluoromethyl)acetophenone 
• 454-89-7 3-Trifluoromethylbenzaldehyde 
• 2740-83-2 3-(TRIFLUOROMETHYL)BENZYLAMINE 
• 615-43-0 2-iodophenylamine 
• 126507-54-8 benzothiazole-2-ylmagnesium chloride 
• 88-73-3 2-Chloronitrobenzene 
• 705-29-3 3-Trifluoromethylbenzyl chloride 
• 351-35-9 3-(trifluoromethyl)phenylacetic acid 

Relevant articles and documents

Inkable CF3-functionalized benzothiazole/benzimidazole-Ir(III) complexes for efficient bilayer-inkjet-printed OLEDs

The inkjet-printed organic light-emitting diodes (OLEDs) are gradually gaining popularity due to their low cost, free vacuum environment, patterning, and large-area display capability, but inkable phosphors are yet less reported. In order to develop inkab

Benzothiazole Synthesis: Mechanistic Investigation of an in Situ-Generated Photosensitizing Disulfide

The use of a visible light absorbing intermediate as a photosensitizer makes a chemical process simple and sustainable, obviating the need for the use of chemical additives. Herein, the formation of a photosensitizing disulfide in benzothiazole synthesis from 2-Aminothiophenol and aldehydes was proposed and confirmed through in-depth mechanistic studies. A series of photophysical and electrochemical investigations revealed that an in situ-generated disulfide photosensitizes molecular oxygen to generate the key oxidants, singlet oxygen and superoxide anion, for the dehydrogenation step.

Cuprous cluster as effective single-molecule metallaphotocatalyst in white light-driven C[sbnd]H arylation

This study investigated a series of ferrocenyltelluroether based cuprous halide clusters as effective single-molecule metallaphotocatalysts (SMP) in white light-driven C[sbnd]H arylation at room temperature and air. A systematic mechanistic study reveals that Cu(I) cluster can be irradiated by visible light to promote proton-coupled electron transfer (PCET), during which the electron from Cu(I)* leaves together with the proton from benzothiazole C[sbnd]H, leading to the formation of benzothiazolate-coordinated Cu(II) intermediate and aryl radical. Subsequently, the electron transfer (ET) from the ferrocene unit to the Cu(II) center releases the reactive benzothiazolate to form the target product with aryl radical. The advantages of these copper(I) halide clusters as SMP include high photocatalytic efficiency, structure adjustability, mild reaction conditions and good functional group tolerance.