13349-96-7

Basic information

• Product Name: 4-(hexylthio)phenol
• Synonyms: 4-(hexylthio)phenol
• CAS NO: 13349-96-7
• Molecular Weight: 210.34
• Mol File: 13349-96-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-(hexylthio)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(hexylthio)phenol(13349-96-7)
• EPA Substance Registry System: 4-(hexylthio)phenol(13349-96-7)

Safety Data

• Hazardous Substances Data: 13349-96-7(Hazardous Substances Data)

Upstream product

• 22487-02-1 sodium n-hexylmercaptide 
• 106-41-2 4-bromo-phenol 
• 111-31-9 Hexanethiol 
• 763-29-1 2-Methyl-1-pentene 
• 637-89-8 4-sulfanylphenol 
• 497-19-8 sodium carbonate 
• 123-30-8 4-amino-phenol 
• 111-25-1 1-bromo-hexane 
• 696-63-9 4-Methoxybenzenethiol 
• 156-43-4 4-Ethoxyaniline 
• 59693-90-2 n-hexyl 4-methoxyphenyl sulfide 

Relevant articles and documents

Mono- And Dinuclear α-Diimine Nickel(II) and Palladium(II) Complexes in C-S Cross-Coupling

The usefulness of transition metal catalytic systems in C-S cross-coupling reactions is significantly reduced by air and moisture sensitivity, as well as harsh reaction conditions. Herein, we report four highly air- and moisture-stable well-defined mononuclear and bridged dinuclear α-diimine Ni(II) and Pd(II) complexes for C-S cross-coupling. Various ligand frameworks, including acenaphthene- and iminopyridine-based ligands, were employed, and the resulting steric properties of the catalysts were evaluated and correlated with reaction outcomes. Under aerobic conditions and low temperatures, both Ni and Pd systems exhibited broader substrate scope and functional group tolerance than previously reported catalysts. Over 40 compounds were synthesized from thiols containing alkyl, benzyl, and heteroaryl groups. Also, pharmaceutically active heteroaryl moieties are incorporated from thiol and halide sources. Notably, the bridged dinuclear five-coordinate Ni complex has outperformed the remaining three mono four- or six-coordinate complexes by giving almost quantitative yields across a broad substrate scope.

Mercapto phenolic and alkylthio phenolic antioxidants

2-Mercapto phenol and/or 4-mercapto phenol are reacted with a compound selected from olefins, alcohols, and organic halides for example, styrene and isobutylene, to form (hydrocarbyl) thio phenolic antioxidants such as 2,6-di-tert. butyl-4-(tert.butylthio) phenol and 2,6-di(α-phenylethyl)-4-(α-phenylethylthio)phenol.