1335436-87-7

Basic information

• Product Name: [p-(trifluoromethyl)phenyl](diacetoxy)-λ3-bromane
• Synonyms: [p-(trifluoromethyl)phenyl](diacetoxy)-λ3-bromane
• CAS NO: 1335436-87-7
• Molecular Weight: 343.097
• Mol File: 1335436-87-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [p-(trifluoromethyl)phenyl](diacetoxy)-λ3-bromane(CAS DataBase Reference)
• NIST Chemistry Reference: [p-(trifluoromethyl)phenyl](diacetoxy)-λ3-bromane(1335436-87-7)
• EPA Substance Registry System: [p-(trifluoromethyl)phenyl](diacetoxy)-λ3-bromane(1335436-87-7)

Safety Data

• Hazardous Substances Data: 1335436-87-7(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 206753-28-8 difluoro[4-(trifluoromethyl)phenyl]-λ³-bromane 

Downstream Products

• 957188-75-9 [N-(trifluoromethylsulfonyl)imino][4-(trifluoromethyl)phenyl]-λ³-bromane 

Relevant articles and documents

Metal-free C-H amination of unactivated hydrocarbons with sulfonylimino-λ3-bromanes generated in situ from (diacetoxybromo)benzene

A simple method for direct metal-free C-H amination of unactivated hydrocarbons using easy-handling diacetoxy-λ3-bromane and triflylamide or sulfamate esters was developed. The high 2°/3° regioselectivities and deuterium isotope effects suggest a concerted organonitrenoid transition state, analogous to C-H amination with N-triflylimino-λ3-bromane. This journal is