1351415-86-5Relevant articles and documents
A new selective approach to unsymmetrical siloxanes and germasiloxanes via O-metalation of silanols with 2-methylallylsilanes and 2-methylallylgermanes
Hreczycho, Grzegorz,Pawluc, Piotr,Marciniec, Bogdan
experimental part, p. 2743 - 2746 (2012/01/11)
A scandium(iii) trifluoromethanesulfonate-catalyzed O-metalation of silanols with 2-methylallylsilanes and 2-methylallylgermanes leading to siloxane or germasiloxane bond formation under mild conditions with evolution of isobutylene is described.