1356941-15-5

Basic information

• Product Name: C₁₈H₂₄BOP
• Synonyms: C₁₈H₂₄BOP
• CAS NO: 1356941-15-5
• Molecular Weight: 298.173
• Mol File: 1356941-15-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₂₄BOP(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₂₄BOP(1356941-15-5)
• EPA Substance Registry System: C₁₈H₂₄BOP(1356941-15-5)

Safety Data

• Hazardous Substances Data: 1356941-15-5(Hazardous Substances Data)

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 2004-67-3 4-methyl-4-penten-2-ol 

Downstream Products

• 1356941-26-8 C₁₈H₂₃O₂P 
• 1356941-05-3 C₁₈H₂₆BOP 

Relevant articles and documents

Mechanistic variations in ionic hydrogenation of unsaturated phosphine and amine boranes

Internal hydride transfer occurs when tethered carbocations are generated from unsaturated phosphine or phosphinite boranes. 3-Methylenecyclohexyl-derived boranes 12 or 18 react with MsOH to give ionic hydrogenation products with high syn-selectivity. With unsaturated amine boranes, initial hydrogen evolution gives BH2(OMs) complexes, but IH occurs using excess MsOH in a slower second stage. A diastereoselective reaction occurs from 26b using camphorsulfonic acid (first stage) and MsOH (second stage), affording 33 (68% ee) after hydrolysis.