1360563-84-3

Basic information

• Product Name: C₃₂H₂₈BNO
• CAS NO: 1360563-84-3
• Molecular Weight: 453.391
• Mol File: 1360563-84-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₂H₂₈BNO(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₂H₂₈BNO(1360563-84-3)
• EPA Substance Registry System: C₃₂H₂₈BNO(1360563-84-3)

Safety Data

• Hazardous Substances Data: 1360563-84-3(Hazardous Substances Data)

Upstream product

• 7294-50-0 tri-o-tolylboroxine 
• 130798-48-0 (S)-(-)-α,α-di(2-naphthyl)-2-pyrrolidinemethanol 

Relevant articles and documents

Lewis acid-catalyzed Diels-Alder reaction of 2-cyclopentenones with Danishefsky's diene: Double bond isomerization of tetrahydro-1Hindene- 1,5(7aH)-diones, and attempts on an asymmetric catalysis

This work describes the investigation of the Diels-Alder reaction of the electron-rich diene trans- 1-methoxy-3-trimethylsilyloxy-1,3-butadiene (Danishefsky's diene) and the non-activated dienophiles 2-cyclopentenone and 2-methyl-2-cyclopentenone with respect to reactivity, regioselectivity and stereoselectivity. An observed double bond isomerization limits the practicability of 2-cyclopentenone as a dienophile in Diels-Alder reactions. 2-Methyl-2- cylopentenone could be converted quantitatively into one regioisomeric Diels-Alder adduct, however the stereochemical control turned out to be very demanding. ARKAT-USA, Inc.