1370639-85-2Relevant articles and documents
Mild isomerative opening of tetrahydrofuranyl subunits in steroids using TFAT (trifluoroacetyl trifluoromethanesulfonate): Application to synthesis of C17-OH rockogenin acetate
Lee, Jong Seok,Kim, Byungsook,Shin, Junho,Lee, Yeon-Ju,Shin, Hee Jae,Lee, Hyi-Seung
experimental part, p. 76 - 82 (2012/03/22)
A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condi