1383475-80-6

Basic information

• Product Name: diethyl((2S,3R,E)-2-nitro-3-(nitromethyl)-5-phenylpent-4-en-2-yl)phosphonate
• CAS NO: 1383475-80-6
• Molecular Weight: 386.342
• Mol File: 1383475-80-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl((2S,3R,E)-2-nitro-3-(nitromethyl)-5-phenylpent-4-en-2-yl)phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl((2S,3R,E)-2-nitro-3-(nitromethyl)-5-phenylpent-4-en-2-yl)phosphonate(1383475-80-6)
• EPA Substance Registry System: diethyl((2S,3R,E)-2-nitro-3-(nitromethyl)-5-phenylpent-4-en-2-yl)phosphonate(1383475-80-6)

Safety Data

• Hazardous Substances Data: 1383475-80-6(Hazardous Substances Data)

Upstream product

• 919-19-7 diethyl acetylphosphonate 
• 53145-08-7 diethyl 1-(hydroxyimino)ethylphosphonate 
• 60593-26-2 (1-nitroethyl)-phosphonic acid diethyl ester 

Relevant articles and documents

Catalytic asymmetric synthesis of α,β-disubstituted α,γ-diaminophosphonic acid precursors by michael addition of α-substituted nitrophosphonates to nitroolefins

Michael additions of α-substituted nitrophosphonates to various nitroolefins are shown to proceed with high diastereo- and enantioselectivity when catalyzed by a quinine-derived thiourea-tertiary amine bifunctional catalyst and generate α,γ-diaminophosphonic acid precursors with contiguous quaternary and tertiary stereocenters.