1384164-85-5

Basic information

• Product Name: 1-(n-butyl)-3-(3,4,5-trimethoxybenzyl)benzimidazolium chloride
• Synonyms: 1-(n-butyl)-3-(3,4,5-trimethoxybenzyl)benzimidazolium chloride
• CAS NO: 1384164-85-5
• Molecular Weight: 390.91
• Mol File: 1384164-85-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(n-butyl)-3-(3,4,5-trimethoxybenzyl)benzimidazolium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(n-butyl)-3-(3,4,5-trimethoxybenzyl)benzimidazolium chloride(1384164-85-5)
• EPA Substance Registry System: 1-(n-butyl)-3-(3,4,5-trimethoxybenzyl)benzimidazolium chloride(1384164-85-5)

Safety Data

• Hazardous Substances Data: 1384164-85-5(Hazardous Substances Data)

Upstream product

• 4886-30-0 1-butylbenzimidazole 
• 3840-30-0 5-(chloromethyl)-1,2,3-trimethoxybenzene 

Relevant articles and documents

N-heterocyclic carbene based ruthenium complexes for selective β-C(sp3)-H functionalization of N-fused saturated cyclic amines

Herein, a series of new ruthenium(II) complexes with the general molecular formula [RuCl2(arene)(NHC)], (arene = η6-p-cymene, NHC = N-heterocyclic carbene) were synthesized from in situ prepared silver(I)-NHCs by the transmetallation method. These complexes were fully characterized by analytical and spectral methods. Ruthenium(II) complexes were tested as promising catalyst for selective β-C(sp3)-H functionalization of N-methylpiperidine with various aldehydes through hydrogen transfers in presence of external acidic additive. These eco-friendly cross-dehydrogenative couplings enable the production of C(3)-alkylated N-methylpiperidine derivatives without enamines with only carbon dioxide and water as benign by-product.