138784-60-8

Basic information

• Product Name: Pt(C₆F₅){(C₆H₄)(C₆H₅)CNNC(C₆H₅)2}
• Synonyms: Pt(C₆F₅){(C₆H₄)(C₆H₅)CNNC(C₆H₅)2}
• CAS NO: 138784-60-8
• Molecular Weight: 721.588
• Mol File: 138784-60-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(C₆F₅){(C₆H₄)(C₆H₅)CNNC(C₆H₅)2}(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(C₆F₅){(C₆H₄)(C₆H₅)CNNC(C₆H₅)2}(138784-60-8)
• EPA Substance Registry System: Pt(C₆F₅){(C₆H₄)(C₆H₅)CNNC(C₆H₅)2}(138784-60-8)

Safety Data

• Hazardous Substances Data: 138784-60-8(Hazardous Substances Data)

Upstream product

• 138784-58-4 (C₆F₅)2Pt{(C₆H₅)2CNNC(C₆H₅)2} 
• 983-79-9 benzophenone azine 
• 908093-98-1 diazodiphenylmethane 

Downstream Products

• 138784-61-9 Pt(C₆F₅){(C₆H₄)C(C₆H₅)NNC(C₆H₅)2}(CO) 

Relevant articles and documents

Reactivity of cis-Pt(C6F5)2(OC4H8) 2 toward (C6H5)2CN2. Synthesis and molecular structure of Pt(C6F5)[(2-C6H4)C(C 6H5)=N-N=(η2-C6H 5)C(C6H ...

Full title: Reactivity of cis-Pt(C6F5)2(OC4H8) 2 toward (C6H5)2CN2. Synthesis and molecular structure of Pt(C6F5)[(2-C6H4)C(C 6H5)=N-N=(η2-C6H 5)C(C6H5)], an ortho-metalated compound containing an unusual intramolecular η2-arene-Pt interaction. Treatment of cis-Pt(C6F5)2(OC4H8) 2 (1) with (C6H5)2CN2 (2) affords cis-Pt(C6F5)2[(C6H5) 2C=N-N= C(C6H5)2] (4), which can also be obtained by reacting 1 with (C6H5)2C=N-N=C(C6H5) 2 (3). A possible structure of complex 4 is discussed both in terms of its spectroscopical features and its chemical behavior. 4 undergoes an ortho-metalation process by thermolysis either in solution or in the solid state, yielding Pt(C6F5)[(2-C6H4)C(C 6H5)=N-N=(η2-C6H 5)C(C6H5)] (7), which has been structurally characterized by an X-ray diffraction study. 7 crystallizes in monoclinic space group P21/n with a = 11.8359 (6) A?, b = 14.2561 (7) A?, c = 15.4549 (9) A?, β = 103.200(5)°; V = 2539 (1) A?3, and Z = 4. One of the phenyl rings of the ortho-metalated benzophenone azine is η2-coordinated to platinum, the whole ligand acting as tridentate. The η2-aryl-Pt coordination, present in 7 and postulated in 4, is released by reaction of each compound with CO, thereby giving rise to Pt(C6F5)[(2-C6H4)C(C 6H5)=N-N=C(C6H5)2](CO) (8) and cis-Pt(C6F5)2[(C6H5) 2C=N-N=C(C6H5)2](CO) (5), respectively.