139373-36-7

Basic information

• Product Name: Trifluoro-methanesulfonate(2,2-bis-methoxycarbonyl-propyl)-phenyl-trimethylsilanylmethyl-sulfonium;
• Synonyms: Trifluoro-methanesulfonate(2,2-bis-methoxycarbonyl-propyl)-phenyl-trimethylsilanylmethyl-sulfonium
• CAS NO: 139373-36-7
• Molecular Weight: 504.621
• Mol File: 139373-36-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trifluoro-methanesulfonate(2,2-bis-methoxycarbonyl-propyl)-phenyl-trimethylsilanylmethyl-sulfonium;(CAS DataBase Reference)
• NIST Chemistry Reference: Trifluoro-methanesulfonate(2,2-bis-methoxycarbonyl-propyl)-phenyl-trimethylsilanylmethyl-sulfonium;(139373-36-7)
• EPA Substance Registry System: Trifluoro-methanesulfonate(2,2-bis-methoxycarbonyl-propyl)-phenyl-trimethylsilanylmethyl-sulfonium;(139373-36-7)

Safety Data

• Hazardous Substances Data: 139373-36-7(Hazardous Substances Data)

Upstream product

• 64035-64-9 Trimethylsilylmethyl trifluoromethanesulfonate 
• 139373-18-5 2-Methyl-2-phenylsulfanylmethyl-malonic acid dimethyl ester 

Downstream Products

• 17277-58-6 methyl (phenylsulfanyl)acetate 
• 80-62-6 methacrylic acid methyl ester 

Relevant articles and documents

A New Fragmentation Reaction of γ-Oxosulfonium Methylides

Reactions of sulfonium methylides attached to a 5- or 6-membered cycloalkanone undergo the ring-fission as a major reaction course to give α-methylene-ω-(phenylthio)carboxylates, whereas sulfonium methylides attached to a larger ring give α-methylenecycloalkanones predominantly.Reactions of the acyclic compounds are also examined.