139583-37-2

Basic information

• Product Name: {C₇H₆(C₆H₅)(C(OC₂H₅))}(CO)Fe(CO)2
• CAS NO: 139583-37-2
• Molecular Weight: 364.181
• Mol File: 139583-37-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {C₇H₆(C₆H₅)(C(OC₂H₅))}(CO)Fe(CO)2(CAS DataBase Reference)
• NIST Chemistry Reference: {C₇H₆(C₆H₅)(C(OC₂H₅))}(CO)Fe(CO)2(139583-37-2)
• EPA Substance Registry System: {C₇H₆(C₆H₅)(C(OC₂H₅))}(CO)Fe(CO)2(139583-37-2)

Safety Data

• Hazardous Substances Data: 139583-37-2(Hazardous Substances Data)

Upstream product

• 13463-40-6 iron pentacarbonyl 
• 754-03-0 ethanesulfonyl fluoride 
• 542-92-7 cyclopenta-1,3-diene 
• 4440-01-1 lithium phenylacetylide 

Downstream Products

• 139583-38-3 {C₇H₆(C₆H₅)(CHO)}Fe(CO)3 

Relevant articles and documents

Reactions between iron(0) alkynylcarbene complexes and cyclopentadiene: Formation of iron(0) η1-vinylcarbene complexes and their facile thermal transformation into the corresponding (η3:η1-allylacyl)iron(II) complexes

[(3-tert-Butylnorbornadienyl)ethoxymethylene]Fe(CO)4, the iron(0) η1-vinylcarbene complex 2, is obtained from the reaction of [(3,3-dimethylbutynyl)ethoxymethylene]Fe(CO)4 (1a) with cyclopentadiene at 25°C. Complex 2 transforms into the η3:η1-allylacyl complex 4a via a CO insertion reaction at the original carbene carbon by heating at 50°C for 1 h. However, direct formation of η3:η1-allylacyl complexes is observed in reactions of cyclopentadiene with other alkynylcarbene complexes, 1b (R = SiMe3), 1c (R = cyclohexyl), 1d (R = n-propyl), and 1e (R = phenyl), at 25°C.