14060-53-8Relevant articles and documents
Uebergangsmetall-Fulven-Komplexe XXXIII. Synthese und Struktur von Fulven-Komplexen des Cobalts und Rhodiums
Rau, Doris,Behrens, Ulrich
, p. 219 - 231 (1990)
Diarylfulvenes react with (C5H5)Co(C2H4)2 to give the η4-coordinated fulvene complexes (C5H5)2Co(fulvene) (3).Reaction of (C5H5)Rh(C2H4)2 or (C9H7)Rh(C2H4)2 (C9H7 = indenyl) with diphenylfulvene yields the compounds (C5H5)Rh(η4-fulve
Method for producing fulvene
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Paragraph 0040, (2017/03/08)
PROBLEM TO BE SOLVED: To provide a method for producing a fulvene in which the reaction efficiently proceeds regardless of the nature of the substituent group which a raw-material ketone, especially a ketone not having an α-proton, possesses. SOLUTION: Provided is a method for producing a fulvene including a step to condense a ketone not possessing an α-proton, and an alkali metal salt of cyclopentadiene in the presence of a Lewis acid. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT