142753-36-4

Basic information

• Product Name: Acetic acid, fluoro(phenylseleno)-, ethyl ester
• CAS NO: 142753-36-4
• Molecular Formula: C10H11FO2Se
• Molecular Weight: 261.155
• Mol File: 142753-36-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Acetic acid, fluoro(phenylseleno)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, fluoro(phenylseleno)-, ethyl ester(142753-36-4)
• EPA Substance Registry System: Acetic acid, fluoro(phenylseleno)-, ethyl ester(142753-36-4)

Safety Data

• Hazardous Substances Data: 142753-36-4(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 401-56-9 ethyl chlorofluoroacetate 
• 51364-94-4 ethyl 2-(phenylselanyl)acetate 

Downstream Products

• 864363-40-6 fluoro-(1-hydroxy-4-phenyl-cyclohexyl)-phenylselanyl-acetic acid ethyl ester 
• 20397-59-5 ethyl (Z)-2-fluoro-3-phenylacrylate 
• 864363-32-6 2-fluoro-3-hydroxy-3-(4-methoxy-phenyl)-2-phenylselanyl-propionic acid ethyl ester 
• 864363-39-3 fluoro-(1-hydroxy-cyclopentyl)-phenylselanyl-acetic acid ethyl ester 
• 1666-13-3 diphenyl diselenide 
• 868775-00-2 α-fluoro-α-(phenylselanyl)acetaldehyde diethyl acetal 
• 308335-59-3 ethyl 2-(phenylselanyl)pent-4-enoate 
• 140870-79-7 2-fluoro-2-(phenylselanyl)acetonitrile 
• 72041-41-9 ethyl-α,α-bis(phenylseleno) acetate 
• 14370-82-2 allyl phenyl selenide 

Relevant articles and documents

Scandium-catalyzed carbon-carbon bond formations using α- organosulfanyl and organoselanyl-α-fluoroacetic acid derivatives

The scandium-catalyzed reactions of α-organosulfanyl and organoselanyl-α-fluoroacetates 1-2, acetamides 3-4 and acetonitrile 5 with soft nucleophiles proceeded to give the products 6a-b, 7a-c, 8a-c, 9a-e in good to high yields. We also successfully perfor

First Lewis acid catalyzed generation and reaction of α- organylsulfanyl and α-organylselanyl carbenium ions using ethyl α-fluoroacetate derivatives

Lewis acid catalyzed generation and reactions of α-organylsulfanyl and α-organylselanyl carbenium ions with nucleophiles proceeded in high yields using α-fluoro-α-organylsulfanyl- and α-fluoro-α- organylselanylacetate and 5 mol-% scandium triflate. Wiley-

Electrosynthesis of ethyl α, α-difluoro-α-(phenylseleno)acetate and its photochemical synthetic application

Anodic fluorination of ethyl α-fluoro-α-(phenylseleno) acetate was successfully carried out to give ethyl α,α -difluoro-α-(phenylseleno)acetate in high yield. Photolysis of the difluorinated product in the presence of various olefins provided regioselective difluorometylene adducts in good to moderate total yields. The reaction involves phenylselenyl transfer at the early stage followed by the elimination of a phenylselenyl group from the adducts once formed to provide the unsaturated and saturated difluoromethylene products.