1430342-19-0

Basic information

• Product Name: (3-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate
• Synonyms: (3-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate
• CAS NO: 1430342-19-0
• Molecular Weight: 490.257
• Mol File: 1430342-19-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (3-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (3-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate(1430342-19-0)
• EPA Substance Registry System: (3-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate(1430342-19-0)

Safety Data

• Hazardous Substances Data: 1430342-19-0(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 1121-86-4 1-Fluoro-3-iodobenzene 
• 108-67-8 1,3,5-trimethyl-benzene 

Downstream Products

• 1430342-32-7 2-(3-fluorophenyl)-1-phenylpropan-1-one 
• 1430342-26-9 2-(3-fluorophenyl)-3-hydroxy-1-phenylpropan-1-one 
• 1073-06-9 3-fluorobromobenzene 
• 1618656-95-3 3-(3-fluorobenzyl)-1,3-dimethylindolin-2-one 

Relevant articles and documents

A Modular Synthesis of 4-Aminoquinolines and [1,3] N-to-C Rearrangement to Quinolin-4-ylmethanesulfonamides

A copper-catalyzed regiocontrolled three-component reaction afforded diversified 4-aminoquinolines using nitriles, diaryliodoniums, and ynamides. The C7-substituted regioisomers were formed regioselectively when meta-substituted phenyliodonium salts were used. [1,3] N-to-C rearrangement of the products to quinolin-4-ylmethanesulfonamides and simultaneous deprotection of benzyl and sulfonamide group were newly developed. Finally, antimalarial CK-2-68 was successfully prepared.

Palladium-catalyzed P(O)R2 directed C-H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

Palladium-catalyzed arylation of (diisopropylphosphoryl)biphenyl skeleton derivatives by the P(O)R2 directed C-H functionalization was reported. The related products were obtained in high regioselectivity and good functional group tolerance was observed. This reaction provided a new and efficient pathway for the synthesis of polyaromatic monophosphorus ligands. The Royal Society of Chemistry.