14374-57-3

Basic information

• Product Name: 1-methoxy-4-(pent-1-en-1-yl)benzene
• CAS NO: 14374-57-3
• Molecular Weight: 176.258
• Mol File: 14374-57-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-methoxy-4-(pent-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-4-(pent-1-en-1-yl)benzene(14374-57-3)
• EPA Substance Registry System: 1-methoxy-4-(pent-1-en-1-yl)benzene(14374-57-3)

Safety Data

• Hazardous Substances Data: 14374-57-3(Hazardous Substances Data)

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 123-11-5 4-methoxy-benzaldehyde 
• 19523-03-6 1-(4-methoxyphenyl)pentanol 
• 1779-51-7 n-butyl(triphenyl)phosphonium bromide 
• 16034-99-4 1-(2-bromopropenyl)-4-methoxybenzene 
• 925-90-6 ethylmagnesium bromide 
• 75619-34-0 Benzyltris-(p-methoxyphenyl)phosphonium bromide 
• 855-38-9 P(p-CH₃OC₆H₄)3 
• 75619-30-6 Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane 
• 123-72-8 butyraldehyde 

Downstream Products

• 76968-29-1 4-(4-Methoxy-phenyl)-5-propyl-[1,3]dioxane 
• 856338-86-8 1-(4-methoxy-phenyl)-pentane-1,2-diol 
• 18657-10-8 (E)-1-methoxy-4-(pent-1-en-1-yl)benzene 
• 7642-16-2 (Z)-1-methoxy-4-(pent-1-en-1-yl)benzene 
• 146232-40-8 2-(4-methoxyphenyl)valeraldehyde 
• 1021934-33-7 2-bromo-1-(4-methoxyphenyl)pentan-1-ol 
• 14938-35-3 4-n-pentylphenol 
• 20056-58-0 1-(4-Methoxyphenyl)pentane 
• 860585-64-4 4-(1,2-dibromo-pentyl)-anisole 
• 1671-76-7 p-Methoxyvalerophenon 

Relevant articles and documents

Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

A new efficient method for the synthesis of a high ratio of E -alkenes from E / Z mixtures of alkenes with B 2pin 2in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.

Untersuchungen im Wittig-System nach einem ordnenden Konzept auf der Basis alternativer Prinzipien

Our results show that the stereoselectivity of the Wittig-reaction can be controlled by the variation of substituents in accord with the ORDERING CONCEPT OF ALTERNATIV PRINCIPLES (individual pairs, known and unknown classes of alternatives).The "all-phenyl Wittig-system" having three phenyl groups on phosphorous two in ylid- and aldehyd-position was chosen as a standard for our investigations.Differentiation in ylid-position and compensation on phosphorous and aldehyd-position were observed by the comparison of "patterns".Consequently, most of the selectivity rules of Wittig-reactions can be explained by the differentiation through alternatives in the ylid-position.Inversion or conservation of the "patterns" of measured data points to the variation in structure of starting materials, reaction rates and selectivities.Amount-controls were also described in certain systems.

REACTIONS EN MILIEU HETEROGENE SOLIDE-LIQUIDE FAIBLEMENT HYDRATE : LA REACTION DE WITTIG DANS LE SYSTEME HYDROXIDES ALCALINS/SOLVANT ORGANIQUE APROTIQUE

The Wittig reaction carried out in a slightly hydrated solid-liquid media constituted by a solid alkaline hydroxide and an organic phase which includes the phosphonium salt and the aldehyde leads easily to the corresponding alkene with very good yields specially with furanic aldehydes.The ylide formation at the interface appears as the most important step of this condensation.