1438894-51-9

Basic information

• Product Name: m-methylphenylphenylmethanol acetate
• Synonyms: m-methylphenylphenylmethanol acetate
• CAS NO: 1438894-51-9
• Molecular Weight: 240.302
• Mol File: 1438894-51-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: m-methylphenylphenylmethanol acetate(CAS DataBase Reference)
• NIST Chemistry Reference: m-methylphenylphenylmethanol acetate(1438894-51-9)
• EPA Substance Registry System: m-methylphenylphenylmethanol acetate(1438894-51-9)

Safety Data

• Hazardous Substances Data: 1438894-51-9(Hazardous Substances Data)

Upstream product

• 620-47-3 1-methyl-3-(phenylmethyl)-benzene 
• 64-19-7 acetic acid 

Downstream Products

• 643-65-2 3-methyl benzophenone 

Relevant articles and documents

Metal-Free Aerobic Oxidative C–O Coupling of C(sp3)–H with Carboxylic Acids Catalyzed by DDQ and tert-Butyl Nitrite

The formation of the C–O bond is one of the hot topics in the area of C(sp3)–H bond functionalization. A metal-free oxidative cross-coupling between benzylic C(sp3)–H bond and carboxylic acids has been developed. The reactions were performed with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as the catalyst, tert-butyl nitrite (TBN) as the co-catalyst, and molecular oxygen as the terminal oxidant. A variety of diarylmethanes could be successfully coupled with various carboxylic acids to obtain diarylmethanol esters in good to excellent yields. In addition, 2-benzylbenzoic acids could be converted into phthalides in moderate yields through an intramolecular oxidative cyclization.