14884-70-9

Basic information

• Product Name: N-Benzyl-N,α,α,α-tetramethylsilanamine
• Synonyms: (Methylbenzylamino)trimethylsilane;N-Benzyl-N,α,α,α-tetramethylsilanamine;N-Methyl-N-trimethylsilylbenzylamine
• CAS NO: 14884-70-9
• Molecular Formula: C₁₁H₁₉NSi
• Molecular Weight: 193.3608
• Mol File: 14884-70-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 227.8°Cat760mmHg
• Flash Point: 91.6°C
• Appearance: /
• Density: 0.9g/cm³
• Vapor Pressure: 0.114mmHg at 25°C
• Refractive Index: 1.49
• CAS DataBase Reference: N-Benzyl-N,α,α,α-tetramethylsilanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzyl-N,α,α,α-tetramethylsilanamine(14884-70-9)
• EPA Substance Registry System: N-Benzyl-N,α,α,α-tetramethylsilanamine(14884-70-9)

Safety Data

• Hazardous Substances Data: 14884-70-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H19NSi/c1-12(13(2,3)4)10-11-8-6-5-7-9-11/h5-9H,10H2,1-4H3

Upstream product

• 34592-98-8 N-methyl-α-(trimethylsilyl)benzylamine 
• 75-77-4 chloro-trimethyl-silane 
• 103-67-3 benzyl-methyl-amine 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Downstream Products

• 75-77-4 chloro-trimethyl-silane 
• 82942-81-2 N,N'-Dibenzyl-N,N'-dimethylsulfinyldiamin 
• 59791-11-6 1-(N-methyl-N-benzyl)amino-6-methyl-1,3-dihydrofuro[3,4-c]pyridin-7-ol 

Relevant articles and documents

Nucleophilic bromodifluoromethylation of iminium ions

A method for bromodifluoromethylation of iminium ions using Me3SiCF2Br is described. The reaction involves room temperature activation of the silicon reagent by HMPA to generate difluorocarbene, which upon interacting with excess of bromide ion provides bromodifluoromethyl carbanionic species. The iminium electrophiles are generated in situ from aldehydes, secondary amines, proton sponge, and silyl triflate. The reaction can be extended for introduction of chlorodifluoromethyl and iododifluoromethyl groups.

Co2(CO)8-Catalyzed Ring-Opening Carbonylation of Cyclic Ethers Using N-Silylamines

Co2(CO)8-catalyzed ring-opening carbonylation of oxiranes and oxetane smoothly proceeds with high regioselectivity under 1 atm of carbon monoxide at room temperature to give the corresponding β- and γ-siloxy amides in high yields, respectively. 1R2>+- is thought to be an active catalyst species and directs the high regioselectivity of the carbonylation.