15051-19-1

Basic information

• Product Name: Ni(CO)2(dimethylaminodifluorophosphine)2
• Synonyms: Ni(CO)2(dimethylaminodifluorophosphine)2
• CAS NO: 15051-19-1
• Molecular Weight: 340.805
• Mol File: 15051-19-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(CO)2(dimethylaminodifluorophosphine)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(CO)2(dimethylaminodifluorophosphine)2(15051-19-1)
• EPA Substance Registry System: Ni(CO)2(dimethylaminodifluorophosphine)2(15051-19-1)

Safety Data

• Hazardous Substances Data: 15051-19-1(Hazardous Substances Data)

Upstream product

• 814-97-1 (dimethylamino)difluorophosphine 
• 13463-39-3 tetracarbonyl nickel 

Downstream Products

• 15053-92-6 Ni(dimethylaminodifluorophosphine)4 
• 13463-39-3 tetracarbonyl nickel 

Relevant articles and documents

Phosphorus-fluorine chemistry. V. Dialkylaminodifluorophosphines and their coordination compounds with transition metals

The substituted phosphorus fluorides (CH3)2NPF2, (C2H5)2NPF2, and C5H10NPF2 (C5H10 = piperidyl) have been prepared by fluorinating the corresponding chlorides R2NPCl2 with SbF3 or a suspension of NaF in tetramethylene sulfone. These substituted phosphorus fluorides serve as interesting ligands which will displace CO from nickel and molybdenum carbonyls to give compounds of the type Ni(CO)2L2, NiL4, and Mo(CO)3L3 (L is any of the new fluorides).