1512847-12-9

Basic information

• Product Name: C1′-epi-digitoxin
• Synonyms: C1′-epi-digitoxin
• CAS NO: 1512847-12-9
• Molecular Weight: 764.951
• Mol File: 1512847-12-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C1′-epi-digitoxin(CAS DataBase Reference)
• NIST Chemistry Reference: C1′-epi-digitoxin(1512847-12-9)
• EPA Substance Registry System: C1′-epi-digitoxin(1512847-12-9)

Safety Data

• Hazardous Substances Data: 1512847-12-9(Hazardous Substances Data)

Upstream product

• 1512847-00-5 phenyl 3-O-benzyl-2,6-dideoxy-β-D-ribo-hexapyranosyl-(1→4)-3-O-benzyl-6-deoxy-2-O-methyl-1-thio-α-D-ribo-hexopyranoside 
• 1512853-02-9 C₁₈H₃₀O₉ 
• 1512847-08-3 C₄₆H₅₆O₁₀S 
• 1512846-97-7 C₃₉H₅₄O₇SSi 
• 1512846-69-3 phenyl 3-O-benzyl-6-deoxy-2-O-methyl-1-thio-α-D-ribohexopyranoside 
• 1512846-74-0 phenyl 3-O-benzyl-2-O-methyl-6-O-p-toluenesulfonyl-1-thio-α-D-ribohexopyranoside 
• 1512846-73-9 phenyl 3-O-benzyl-2-O-methyl-1-thio-α-D-ribohexopyranoside 
• 1450628-85-9 1,2,4,6-tetra-O-acetyl-3-O-benzylallopyranose 
• 1512847-14-1 3,4-Di-O-tert-butyldimethylsilyl-2,6-dideoxy-β-D-ribo-hexapyranosyl-(1→4)-3-O-tert-butyldimethylsilyl-2,6-dideoxy-β-D-ribohexapyranosyl-(1→4)-1,5-anhydro-3-O-tert-butyldimethylsilyl-2,6-dideoxy-D-ribo-hex-1-enitol 
• 1512847-06-1 2,6-dideoxy-3,4-bis-O-(triethylsilyl)-β-D-ribohexapyranosyl-(1→4)-2,6-dideoxy-3-O-triethylsilyl-β-D-ribo-hexapyranosyl-(1→4)-1,5-anhydro-2,6-dideoxy-3-O-triethylsilyl-D-ribo-hex-1-enitol 
• 1512847-02-7 phenyl 3-O-benzyl-4-O-tert-butyldimethylsilyl-2,6-dideoxy-β-D-ribohexapyranosyl-(1→4)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexapyranosyl-(1→4)-3-O-benzyl-6-deoxy-2-O-methyl-1-thio-α-D-ribohexopyranoside 

Relevant articles and documents

Catalytic stereoselective synthesis of β-digitoxosides: Direct synthesis of digitoxin and C1′-epi-digitoxin

A mild and atom-economic rhenium(V)-catalyzed stereoselective synthesis of β-d-digitoxosides from 6-deoxy-d-allals has been described. This β-selective glycosylation was achieved probably because of the formation of corresponding α-digitoxosides disfavored by 1,3-diaxial interaction. In addition, this method has been successfully applied to the synthesis of digitoxin trisaccharide glycal for the direct synthesis of digitoxin and C1′-epi-digitoxin.