153924-62-0

Basic information

• Product Name: METHYL 2-PHENYL-2-[(PHENYLMETHYLENE)AMINO]ACETATE
• Synonyms: METHYL 2-PHENYL-2-[(PHENYLMETHYLENE)AMINO]ACETATE
• CAS NO: 153924-62-0
• Molecular Formula: C₁₆H₁₅NO₂
• Molecular Weight: 253.3
• Mol File: 153924-62-0.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 360.2±35.0 °C(Predicted)
• Appearance: /
• Density: 1.05±0.1 g/cm3(Predicted)
• PKA: 2.32±0.50(Predicted)
• CAS DataBase Reference: METHYL 2-PHENYL-2-[(PHENYLMETHYLENE)AMINO]ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 2-PHENYL-2-[(PHENYLMETHYLENE)AMINO]ACETATE(153924-62-0)
• EPA Substance Registry System: METHYL 2-PHENYL-2-[(PHENYLMETHYLENE)AMINO]ACETATE(153924-62-0)

Safety Data

• Hazardous Substances Data: 153924-62-0(Hazardous Substances Data)

Upstream product

• 15028-40-7 DL-2-phenylglycine methyl ester hydrochloride 
• 100-52-7 benzaldehyde 
• 24461-61-8 phenylglycine methyl ester 

Downstream Products

• 75516-80-2 (2R,3R,4R,5R)-2,5-Diphenyl-pyrrolidine-2,3,4-tricarboxylic acid trimethyl ester 
• 75516-80-2 (2S,3S,4S,5R)-2,5-Diphenyl-pyrrolidine-2,3,4-tricarboxylic acid trimethyl ester 
• 75516-80-2 trimethyl 2,t-5-diphenylpyrrolidine-r-2,c-3,t-4-tricarboxylate 
• 75516-80-2 trimethyl 2,c-5-diphenylpyrrolidine-r-2,c-3,t-4-tricarboxylate 
• 486-25-9 9-fluorenone 
• 746-47-4 tetrabenzo[5.5]fulvalene 
• 117316-21-9 C₁₆H₁₄⁽²⁾HNO₂ 
• 83529-43-5 Phenyl-{[1-phenyl-meth-(E)-ylidene]-amino}-acetic acid isopropyl ester 
• 15028-39-4 L-2-phenylglycine methyl ester hydrochloride 
• 19883-41-1 D-phenylglycine methyl ester hydrochloride 
• 113370-50-6 diphenyl r-2-methoxycarbonyl-2,c-5-diphenylpyrrolodine-c-3,c-4-dicarboxylate 
• 113370-50-6 diphenyl 2,c-5-diphenylpyrrolidine-r-2, c-methoxycarbonyl-3,t-4-dicarboxylate 
• 113370-50-6 diphenyl r-2-methoxycarbonyl-2,t-5-diphenylpyrrolodine-t-3,c-4-dicarboxylate 
• 113370-50-6 diphenyl r-2-methoxycarbonyl-2,t-5-diphenylpyrrolodine-t-3,t-4-dicarboxylate 

Relevant articles and documents

Rh-catalyzed asymmetric hydrogenation of racemic aldimines via dynamic kinetic resolution

Catalyzed by a rhodium complex of P-stereogenic diphosphine ligand trichickenfootphos (TCFP), asymmetric hydrogenation of racemic aldimines via dynamic kinetic resolution has been realized for the preparation of chiral arylglycines with good yields and enantioselectivities.

Novel highly functionalized benzoylaminocarbothioyl pyrrolidine from benzoylisothiocyanate and substitueted pyrrolidine derived from α-aminoasit ester via imine -azomethine ylide-1,3-dipolar cycloaddition cascade

A series of novel highly functionalized benzoylaminocarbothioyl pyrrolidines were prepared by the reaction of benzoylisothiocyanate with substitueted pyrrolidine derived from α -aminoasit ester via metal catalsed imine -azomethine ylides-1,3-Dipolar Cycloaddition in excellent yield. An example of chiral version benzoylaminocarbothioyl pyrrolidine were also reported. The chirality oryginated from menthyl acrylate as chiral dipolarophile in the cycloaddition cascade and induced three novell chiral centres.

PHOSPHINOTHRICIN AND ITS DERIVATIVES. I. SYNTHESIS AND EQUILIBRIUM CH ACIDITY OF ESTERS OF N-BENZYLIDENEAMINO(ARALKYL) CARBOXYLIC ACIDS

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