155339-14-3Relevant articles and documents
Synthesis of acylsilanes by copper(I)-catalyzed addition of silicon nucleophiles onto acid derivatives
Cirriez, Virginie,Rasson, Corentin,Riant, Olivier
, p. 3137 - 3140 (2013)
The transition metal-catalyzed transfer of silicon nucleophiles onto various electrophiles has recently gained considerable attention, due to the now readily available silicon pro-nucleophiles such as silylboronates. Our interest lies in the addition of such species to acid derivatives for the generation of acylsilanes. We report herein an efficient method to synthesize these compounds, starting from easy-to-form anhydrides, with very good yields. Copyright
Synthesis of functionalized acylsilanes from carboxylic acid chlorides and silyl-zinc cyanocuprates
Bonini,Comes-Franchini,Mazzanti,Passamonti,Ricci,Zani
, p. 92 - 96 (2007/10/02)
The high yielding synthesis of a variety of acylsilanes, most of them unknown and bearing reactive functionalities, has been accomplished by reaction between carboxylic acid chlorides and a novel silyl-zinc cyanocuprate acting as a silyl anion source. The advantages offered by this procedure with respect to those previously reported, based on carboxylic acid chlorides or on different starting materials, as well as with respect to the use of standard silyl cyanocuprates, are discussed herein.
