155566-51-1 Usage
Description
[1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)is a chemical compound that features a biphenyl structure with a hydroxyl group (-OH) and a diphenylphosphino group (-PPh2) attached to the 2' carbon. [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)is known for its ability to act as a ligand in coordination chemistry, forming complexes with metal centers that exhibit various catalytic and structural properties. It is also utilized in organic synthesis and serves as a reagent in certain chemical reactions. Furthermore, it holds potential applications in the pharmaceutical and materials science industries, making it a versatile and valuable compound in the field of chemistry and related disciplines.
Uses
Used in Coordination Chemistry:
[1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)is used as a ligand in coordination chemistry for forming metal complexes. These complexes possess diverse catalytic and structural properties, which are essential for various chemical reactions and processes.
Used in Organic Synthesis:
In the field of organic synthesis, [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)is employed as a reagent. Its unique structure and functional groups enable it to participate in a range of chemical reactions, contributing to the synthesis of complex organic molecules.
Used in Pharmaceutical Applications:
[1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)has potential applications in the pharmaceutical industry. Its ability to form complexes with metal centers and its involvement in chemical reactions make it a promising candidate for the development of new drugs and therapeutic agents.
Used in Materials Science:
In materials science, [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)is utilized for its potential to contribute to the development of new materials with unique properties. Its coordination chemistry and reactivity in organic synthesis can lead to the creation of advanced materials with applications in various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 155566-51-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,5,5,6 and 6 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 155566-51:
(8*1)+(7*5)+(6*5)+(5*5)+(4*6)+(3*6)+(2*5)+(1*1)=151
151 % 10 = 1
So 155566-51-1 is a valid CAS Registry Number.
155566-51-1Relevant articles and documents
Convenient synthesis of tropos phosphine-oxazoline ligands
Liu, Yuanyuan,Yang, Guoqiang,Yao, Dongmei,Tian, Fengtao,Zhang, Wanbin
experimental part, p. 87 - 94 (2011/12/15)
Tropos phosphine-oxazoline ligands have shown interesting coordination behavior and excellent chiral inducing ability in asymmetry catalysis. Here we present a convenient and economic route for the synthesis of this type of ligands. According to this new route, the ligands with different electronic and steric properties have been prepared successfully.
A novel selective aza-Morita-Baylis-Hillman (aza-MBH) domino reaction and aza-MBH reaction of N-sulfonated imines with acrolein catalyzed by a bifunctional phosphine organocatalyst
Meng, Xiangtai,Huang, You,Chen, Ruyu
supporting information; experimental part, p. 6852 - 6856 (2009/07/18)
An efficient, bifunctional phosphine organocatalyst catalyzed aza-MBH reaction and aza-MBH domino reaction was developed between N-sulfonated imines and acrolein under mild conditions in moderate to excellent yields. Acrolein was added to a solution of N-(2-chlorobenzylidene)-4-methylhenzenesulfonamide and catalyst LBBA in CHCl3. The stirring was maintained at room temperature until completion of the reaction. The residue was purified by a flash column chromatography to yield 3a as a colorless solid. The OH group is utilized to stabilize the intermediate A through hydrogen bonding. The Michael addition of A with N-sulfonated imine gives intermediate B, when THF is used as the solvent. The aza-MBH/Michael/aldol/dehydrate domino reaction also provides an efficient method to synthesize tetrahydropyridine derivatives, which can be used as building blocks in organic synthesis.
2-Aryl-dibenzo-1,2-oxaphosphorine as a ligand in borane and in Pt(II) complexes
Keglevich, Gyoergy,Szelke, Helga,Kerenyi, Andrea,Imre, Timea,Ludanyi, Krisztina,Dukai, Jozsef,Nagy, Ferenc,Aranyi, Peter
, p. 459 - 463 (2007/10/03)
Optimum conditions for the synthesis of aryl-dibenzo-oxaphosphorines (2) from the corresponding phosphonous chloride (1) were explored to avoid the formation of by-products (e.g., 4-6). The aryl-dibenzo-oxaphosphorines (2) were converted to the P-oxides (
