155897-13-5

Basic information

• Product Name: (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (2E)-3-[(2R)-3,4-dihydro-2H-pyran-2-yl]acrylate
• Synonyms: (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (2E)-3-[(2R)-3,4-dihydro-2H-pyran-2-yl]acrylate
• CAS NO: 155897-13-5
• Molecular Weight: 368.516
• Mol File: 155897-13-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (2E)-3-[(2R)-3,4-dihydro-2H-pyran-2-yl]acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (2E)-3-[(2R)-3,4-dihydro-2H-pyran-2-yl]acrylate(155897-13-5)
• EPA Substance Registry System: (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (2E)-3-[(2R)-3,4-dihydro-2H-pyran-2-yl]acrylate(155897-13-5)

Safety Data

• Hazardous Substances Data: 155897-13-5(Hazardous Substances Data)

Upstream product

• 100-73-2 acrolein dimer 
• 155795-46-3 [bis(2,2,2-trifluoroethoxy)phosphoryl]acetic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester 
• 113368-90-4 (Diisopropoxy-phosphoryl)-acetic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 155795-48-5 (diethoxyphosphoryl)acetic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester 

Downstream Products

• 837428-39-4 10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4R,8E)-4-[(diphenylphosphoryl)oxy]deca-2,8-dienedioate 
• 837428-43-0 (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (4R,10R)-10-hydroxy-12-(trimethylsilyl)-4-[2-(trimethylsilyl)ethoxy]dodec-11-ynoate 
• 837428-24-7 10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4R,8E)-4-[2-(trimethylsilyl)ethoxy]deca-2,8-dienedioate 
• 837428-41-8 (4R)-4-[2-(trimethylsilyl)ethoxy]decanedioic acid 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] ester 
• 837428-47-4 (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (4R)-10-hydroxy-4-[2-(trimethylsilyl)ethoxy]decanoate 
• 837428-42-9 (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl (4R)-10-oxo-4-[2-(trimethylsilyl)ethoxy]decanoate 
• 837428-37-2 10-benzyl 1-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl] (2E,4R,8E)-4-hydroxydeca-2,8-dienedioate 

Relevant articles and documents

Total synthesis of pyranicin

(Chemical Equation Presented) A stereocontrolled convergent synthesis of the annonaceous acetogenin pyranicin (1) is presented. Asymmetric Horner-Wadsworth-Emmons (HWE) reactions were used to access key intermediates. The tetrahydropyran derivative 2 was

Kinetische Enantiomerentrennung des Acrolein-Dimers durch asymmetrische Horner-Wadsworth-Emmons-Reaktionen

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