156551-17-6

Basic information

• Product Name: 1-(dimethylphenylsilylmethyl)-1,9-dihydro(C₆₀-I_h)[5,6]fullerene
• Synonyms: 1-(dimethylphenylsilylmethyl)-1,9-dihydro(C₆₀-I_h)[5,6]fullerene
• CAS NO: 156551-17-6
• Molecular Weight: 870.956
• Mol File: 156551-17-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(dimethylphenylsilylmethyl)-1,9-dihydro(C₆₀-I_h)[5,6]fullerene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(dimethylphenylsilylmethyl)-1,9-dihydro(C₆₀-I_h)[5,6]fullerene(156551-17-6)
• EPA Substance Registry System: 1-(dimethylphenylsilylmethyl)-1,9-dihydro(C₆₀-I_h)[5,6]fullerene(156551-17-6)

Safety Data

• Hazardous Substances Data: 156551-17-6(Hazardous Substances Data)

Upstream product

• 107735-20-6 [(dimethylphenylsilyl)methyl]magnesium chloride 
• 99685-96-8 fullerene-C₆₀ 

Downstream Products

• 1342885-09-9 C₆₀(CH₂SiMe₂OMe)Ph 
• 150155-84-3 1,2-dihydromethano[60]fullerene 

Relevant articles and documents

Silylmethylations of C60 with Grignard Reagents: Selective Synthesis of HC60CH2SiMe2Y and C60(CH2SiMe2Y)2 with Selection of Solvents

Addition reactions of Me2SiYCH2MgCl (1) to C60 provided two products, HC60CH2SiYMe2 (2) and 2C60 (3) (Y = Me, H, CH=CH2, Ph, O-iPr).Selective preparation of either 2 or 3 was accomplished by selection of the solvent; 2 was formed in THF, wherea

Regioselective synthesis of 1,4-di(organo)[60]fullerenes through DMF-assisted monoaddition of silylmethyl Grignard reagents and subsequent alkylation reaction

Monoaddition of Grignard reagents, in particular tri(organo) silylmethylmagnesium chlorides, to [60]fullerene took place smoothly in the presence of dimethylformamide to produce (organo)(hydro)[60]fullerenes, C 60C)R1H, in good yield