156642-47-6

Basic information

• Product Name: Benzene, 1-iodo-2-[(2-methyl-2-propenyl)oxy]-
• CAS NO: 156642-47-6
• Molecular Formula: C10H11IO
• Molecular Weight: 274.101
• Mol File: 156642-47-6.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzene, 1-iodo-2-[(2-methyl-2-propenyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-iodo-2-[(2-methyl-2-propenyl)oxy]-(156642-47-6)
• EPA Substance Registry System: Benzene, 1-iodo-2-[(2-methyl-2-propenyl)oxy]-(156642-47-6)

Safety Data

• Hazardous Substances Data: 156642-47-6(Hazardous Substances Data)

Upstream product

• 1458-98-6 2-methyl-3-bromo-1-propene 
• 533-58-4 2-Iodophenol 
• 563-47-3 3-Chloro-2-methylpropene 

Downstream Products

• 13524-78-2 3,3-dimethyl-2,3-dihydrobenzo[b]furan 
• 5820-22-4 methylallyl phenyl ether 

Relevant articles and documents

Palladium-Catalyzed Domino Heck/Sulfination: Synthesis of Sulfonylated Hetero- And Carbocyclic Scaffolds Using DABCO-Bis(sulfur dioxide)

The synthesis of a broad variety of hetero- and carbocyclic scaffolds via a Pd-catalyzed domino Heck/SO2 insertion reaction is reported. This reaction utilizes DABSO, a safe and easy-to-handle alternative to SO2 gas. The reaction proceeds through a sulfin

Formal Bromine Atom Transfer Radical Addition of Nonactivated Bromoalkanes Using Photoredox Gold Catalysis

Organic transformations mediated by photoredox catalysis have been at the forefront of reaction discovery. Recently, it has been demonstrated that binuclear Au(I) bisphosphine complexes, such as [Au2(μ-dppm)2]X2, are capable of mediating electron transfer to nonactivated bromoalkanes for the generation of a variety of alkyl radicals. The transfer reactions of bromine, derived from nonactivated bromoalkanes, are largely unknown. Therefore, we propose that unique metal-based mechanistic pathways are at play, as this binuclear gold catalyst has been known to produce Au(III) Lewis acid intermediates. The scope and proposed mechanistic overview for the formal bromine atom transfer reaction of nonactivated bromoalkanes mediated by photoredox Au(I) catalysis is presented. The methodology presented afforded good yields and a broad scope which include examples using bromoalkanes and iodoarenes.

Microwave-Assisted Domino Heck Cyclization and Phosphorylation: Synthesis of Phosphorus Containing Heterocycles

A domino [Pd]-catalyzed intramolecular Heck cyclization followed by intermolecular phosphorylation, for the construction of phosphorus containing heterocyclic compounds, is presented. Notably, the process is accelerated by microwave heating conditions and enabled the construction of C–C and C–P bonds in short reaction times.