1569906-00-8

Basic information

• Product Name: 1,2,3,4-tetrahydro-[1,2]azaborinino[1,2-a][1,2]azaborinine
• CAS NO: 1569906-00-8
• Molecular Weight: 133.001
• Mol File: 1569906-00-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2,3,4-tetrahydro-[1,2]azaborinino[1,2-a][1,2]azaborinine(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,4-tetrahydro-[1,2]azaborinino[1,2-a][1,2]azaborinine(1569906-00-8)
• EPA Substance Registry System: 1,2,3,4-tetrahydro-[1,2]azaborinino[1,2-a][1,2]azaborinine(1569906-00-8)

Safety Data

• Hazardous Substances Data: 1569906-00-8(Hazardous Substances Data)

Upstream product

• 1569905-99-2 1,4,6,9-tetrahydro-[1,2]azaborinino[1,2-a][1,2]azaborinine 
• 1569905-98-1 (diallylamino)diallylborane 

Relevant articles and documents

Syntheses of [6,6]-fused-ring 1,2-azaborines

BN-naphthalene (2) and BN-tetralin (7) have been prepared by a short synthesis from allyltributylstannane (3). The reaction of 3 with BCl3 followed by diallylamine and Et3N afforded (diallylamino) diallylborane (5), which gave 1,4,5,8-tetrahydro[1,2]azaborino[1,2-a][1,2] azaborine (6), on treatment with Grubbs (I) catalyst. The reaction of 6 with Pd gave 2 and 7. The reaction of 7 with Cr(CO)6 gave the corresponding Cr(CO)3 adduct 8, for which a crystal structure has been obtained. The isomerization of 6 to 7 has been examined using DFT calculations.