157099-67-7Relevant articles and documents
Radical Translocation Reactions across Amides. 1,5-Hydrogen-Transfer Reactions of o-Iodobenzamides and N-(o-Iodobenzyl) Amides
Curran, Dennis P.,Liu, Hohgtao
, p. 1377 - 1394 (2007/10/02)
Radicals derived from N,N-disubstituted o-iodobenzamides undergo rapid 1,5-hydrogen-transfer reactions.The regioselectivity of these reactions is coupled to the rotamer population of the starting iodobenzamide, and the products vary with changing amide substituents.Related 1,5-hydrogen-transfer reactions are observed for N-alkyl-N-(o-iodobenzyl)-benzamides and -acetamides.