15727-47-6Relevant articles and documents
Stereoselective Synthesis of Highly Substituted Tetrahydrofurans through Diverted Carbene O-H Insertion Reaction
Nicolle, Simon M.,Lewis, William,Hayes, Christopher J.,Moody, Christopher J.
, p. 8485 - 8489 (2015)
Copper- or rhodium-catalyzed reactions of diazocarbonyl compounds with β-hydroxyketones give highly substituted tetrahydrofurans with excellent diastereoselectivity. Under mild conditions, the single-step process starts as a carbene O-H insertion reaction, but is diverted by an intramolecular aldol reaction. Gone astray: Copper- or rhodium-catalyzed reactions of diazocarbonyl compounds with β-hydroxyketones give highly substituted tetrahydrofurans with excellent diastereoselectivity. The single-step reaction proceeds under mild conditions, starting as a carbene O-H insertion reaction, but then diverting to an intramolecular aldol reaction.
Palladium-catalyzed decarboxylative sp3-sp3 coupling of nitrobenzene acetic esters
Waetzig, Shelli R.,Tunge, Jon A.
, p. 14860 - 14861 (2008/09/18)
Allylic esters of nitrobenzene acetic acids undergo facile palladium-catalyzed decarboxylative coupling. Both mono- and dinitroarene substrates give high yields of the coupled products. Moreover, the rates of the reactions suggest that decarboxylation is
THE SYNTHESIS, CHARACTERISATION AND REACTIVITY OF SOME LEAD(IV) CARBOXYLATES
Buston, Jonathan E. H.,Coop, Andrew,Keady, Richard,Moloney, Mark G.,Thompson, Russell M.
, p. 1101 - 1116 (2007/10/02)
A detailed examination of the preparation, characterisation and reactivity of a range of lead(IV) carboxylates is reported.The replacement of the acetate ligands of lead(IV) tetraacetate by other carboxylates gives the lead(IV) tetracarboxylates 1-16, which have usually been found to be more stable than lead tetraacetate with respect to hydrolysis.These compounds react with allyltributylstannane to give high yields of the corresponding allyl esters 20-34 under mild conditions.
