158924-95-9

Basic information

• Product Name: Ni(triallylamine)(PPh₃)
• CAS NO: 158924-95-9
• Molecular Weight: 458.206
• Mol File: 158924-95-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(triallylamine)(PPh₃)(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(triallylamine)(PPh₃)(158924-95-9)
• EPA Substance Registry System: Ni(triallylamine)(PPh₃)(158924-95-9)

Safety Data

• Hazardous Substances Data: 158924-95-9(Hazardous Substances Data)

Upstream product

• 14264-16-5 bis(triphenylphosphine)nickel(II) chloride 
• 102-70-5 Triallylamine 

Relevant articles and documents

Chelating Coordination of Di- and Triallylamines: Syntheses and NMR Studies of Trimethylphosphane Nickel and Cobalt Complexes

16-Electron complexes of zerovalent nickel with diallylamines, NiL and 2CH22 (4), were synthesized by reduction of NiCl2L2 with magnesium in tetrahydrofuran.NiCl(ν3-C3H5)2 (5), a low-yield byproduct, was also obtained in high yield from NiL4 and C3H5Cl.With triallylamine as starting material complexes NiL were generated exhibiting ν6- and ν4-olefin coordination, respectively. 17-electron cobalt(0) compounds Co(PMe3)2 (8, 9: R = CH3, C6H5) were obtained by reaction of Co(cyclo-C5H8)(PMe3)3 with the corresponding diallylamine, while CoR(PMe3)4 (R = CH3, C6H5) reacted with N,N-diallylaniline to give diamagnetic Co3-C3H4)(ν2-C3H5)NC6H5>(PMe3)2, (10).The coordination mode of allylic functions was deduced from IR, ESR and especially 1H- and 13C-NMR spectra including 2D-NMR experiments. - Key Words: Allylamine nickel complexes / Allylamine cobalt complexes / 2D NMR, TOCSY