161762-12-5Relevant articles and documents
Radical Cyclization of Bromomethyldimethylsilyl Propargyl Ethers; Synthesis of a Carbocyclic Core of Steroid Skeleton by a Tandem Radical Cyclization
Wu, Sashuang,Journet, Michael,Malacria, Max
, p. 8601 - 8604 (1994)
Homoallyl radical intermediates, generated from the cyclization of bromomethyl-dimethylsilyl propargyl ethers, have been trapped intramolecularly by a double bond in a 6-exo-trig radical process.In that instance, a carbocyclic core of steroid skeleton has