1620193-50-1Relevant articles and documents
Palladium-Catalyzed Electrochemical C-H Bromination Using NH4Br as the Brominating Reagent
Yang, Qi-Liang,Wang, Xiang-Yang,Wang, Tong-Lin,Yang, Xiang,Liu, Dong,Tong, Xiaofeng,Wu, Xin-Yan,Mei, Tian-Sheng
supporting information, p. 2645 - 2649 (2019/04/17)
The palladium-catalyzed electrochemical C-H bromination of benzamide derivatives under divided cells is developed, in which NH4Br serves as a brominating reagent and electrolyte. The protocol avoids the use of chemical oxidants and provides an alternative method for the synthesis of aryl bromides.
Copper-catalyzed direct acyloxylation of C(sp2)-H bonds with Benzoic acids
Zhao, Sheng,Chen, Fa-Jie,Liu, Bin,Shi, Bing-Feng
, p. 1302 - 1309 (2015/03/30)
A copper-catalyzed acyloxylation of C(sp2)-H bond with sterically bulky benzoic acids was achieved. This protocol is compatible with a broad range of functional groups and could proceed in gram scale, providing an efficient and practical protoc
Cu(II)-mediated C-S/N-S bond formation via C-H activation: Access to benzoisothiazolones using elemental sulfur
Chen, Fa-Jie,Liao, Gang,Li, Xin,Wu, Jun,Shi, Bing-Feng
supporting information, p. 5644 - 5647 (2015/02/19)
A copper-mediated C-S/N-S bond-forming reaction via C-H activation that uses elemental sulfur has been developed. The addition of TBAI was found to be crucial for the success of this transformation. The method is scalable, shows excellent functional group tolerance, and is compatible with heterocycle substrates, providing efficient and practical access to benzoisothiazolones. The direct diversification of the benzoisothiazolone products into a variety of sulfur-containing compounds is also demonstrated.
