162225-97-0

Basic information

• Product Name: Carbonic acid allyl ester (2R,4aR,6S,7R,8S,8aS)-8-hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
• Synonyms: Carbonic acid allyl ester (2R,4aR,6S,7R,8S,8aS)-8-hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
• CAS NO: 162225-97-0
• Molecular Weight: 366.368
• Mol File: 162225-97-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Carbonic acid allyl ester (2R,4aR,6S,7R,8S,8aS)-8-hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid allyl ester (2R,4aR,6S,7R,8S,8aS)-8-hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(162225-97-0)
• EPA Substance Registry System: Carbonic acid allyl ester (2R,4aR,6S,7R,8S,8aS)-8-hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester(162225-97-0)

Safety Data

• Hazardous Substances Data: 162225-97-0(Hazardous Substances Data)

Upstream product

• 102423-16-5 allyl 1-benzotriazolyl carbonate 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 2937-50-0 Allyl chloroformate 

Downstream Products

• 162226-16-6 Acetic acid (2R,4aR,6S,7R,8S,8aR)-7-allyloxycarbonyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 2872-56-2 methyl 3-O-acetyl-4,6-O-benzylidene-α-D-glucopyranoside 

Relevant articles and documents

An easy and efficient approach for the installation of alkoxycarbonyl protecting groups on carbohydrate hydroxyls

Alkoxycarbonyl groups can be readily installed on carbohydrates by reaction with the corresponding chloroformates in the presence of TMEDA at low temperature. The mild reaction conditions can be modulated to attain regioselective protections. (C) 2000 Elsevier Science Ltd.