1627203-95-5

Basic information

• Product Name: N-benzoyl cyclohexylmethylsulfoximine
• Synonyms: N-benzoyl cyclohexylmethylsulfoximine
• CAS NO: 1627203-95-5
• Molecular Weight: 265.376
• Mol File: 1627203-95-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzoyl cyclohexylmethylsulfoximine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzoyl cyclohexylmethylsulfoximine(1627203-95-5)
• EPA Substance Registry System: N-benzoyl cyclohexylmethylsulfoximine(1627203-95-5)

Safety Data

• Hazardous Substances Data: 1627203-95-5(Hazardous Substances Data)

Upstream product

• 495-18-1 Benzohydroxamic acid 
• 7133-37-1 cyclohexyl methyl sulfide 
• 19226-36-9 3-phenyl-5H-1,4,2-dioxazol-5-one 

Relevant articles and documents

Light-induced ruthenium-catalyzed nitrene transfer reactions: A photochemical approach towards N-Acyl sulfimides and sulfoximines

1,4,2-Dioxazol-5-ones are five-membered heterocycles known to decarboxylate under thermal or photochemical conditions, thus yielding N-acyl nitrenes. Described herein is a light-induced ruthenium-catalyzed N-acyl nitrene transfer to sulfides and sulfoxides by decarboxylation of 1,4,2-dioxazol-5-ones at room temperature, thus providing direct access to N-acyl sulfimides and sulfoximines under mild reaction conditions. In addition, a one-pot sulfur imidation/oxidation sequence catalyzed by a single ruthenium complex is reported. Double duty: A one-pot sulfur imidation/oxidation sequence using a single ruthenium complex for both steps was developed (see scheme). Photochemical decarboxylations of 1,4,2-dioxazol-5-ones provide N-acyl nitrenes, which imidate sulfides at ambient temperature. The subsequent oxidation then occurs under mild phase-transfer catalysis conditions. In this manner, N-acyl sulfimides and sulfoximines can be obtained in high yields starting from sulfides.