1631051-43-8Relevant articles and documents
Catalytic asymmetric synthesis of 3,3′-diaryloxindoles as triarylmethanes with a chiral all-carbon quaternary center: Phase-transfer- catalyzed snar reaction
Shirakawa, Seiji,Koga, Kenta,Tokuda, Takashi,Yamamoto, Kenichiro,Maruoka, Keiji
supporting information, p. 6220 - 6223 (2014/06/23)
Catalytic asymmetric synthesis of unsymmetrical triarylmethanes with a chiral all-carbon quaternary center was achieved by using a chiral bifunctional quaternary phosphonium bromide catalyst in the SNAr reaction of 3-aryloxindoles under phase-transfer conditions. The presence of a urea moiety in the chiral phase-transfer catalyst was important for obtaining high enantioselectivity in this reaction.