1655-00-1Relevant articles and documents
Production process of cyclohexanecarboxylic acid
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Paragraph 0018; 0023; 0024, (2018/09/08)
The invention discloses a production process of cyclohexanecarboxylic acid and belongs to the field of chemical synthesis. Cyclohexene oxide is used herein as a starting material to react with carbondioxide, Mg powder and TMSCl (trimethylsilyl chloride); Pd/C catalytic hydrogenation is performed in the presence of an acid to obtain the cyclohexanecarboxylic acid. The production process has good safety and good operational simplicity and is suitable for industrial production.
Stereochemistry of the Inhibition of δ-Chymotrypsin with Optically Active cis-Decaline-Type Organophosphates: 31P-NMR Studies
Furegati, Stefan,Ganci, Walter,Przibille, Georg,Rüedi, Peter
, p. 1127 - 1138 (2007/10/03)
Investigation of the inhibition of δ-chymotrypsin with the four novel, optically active, axially and equatorially substituted cis-3-(2,4-dinitrophenoxy)-2,4-dioxa-3λ 5-phosphabicyclo[4.4.0]decan-3-ones (= 3-(2,4-dinitrophenoxy)hexahydro-4H-1,3,
Selective transformation of nitriles into amides and carboxylic acids by an immobilized nitrilase
Klempier,De Raadt,Faber,Grieng
, p. 341 - 344 (2007/10/02)
Using an immobilized nitrilase from Rhodococcus sp. mild and selective hydrolysis of nitriles can be achieved even in the presence of acid or base sensitive groups under neutral conditions. This method is applicable to a broad range of substrates as exemplified by aliphatic, alicyclic, heterocyclic and carbohydrate type nitriles.