1712-84-1

Basic information

• Product Name: bis(4-nitrophenyl)peroxyanhydride
• CAS NO: 1712-84-1
• Molecular Formula: C₁₄H₈N₂O₈
• Molecular Weight: 332.2219
• Mol File: 1712-84-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 526.6°C at 760 mmHg
• Flash Point: 239.1°C
• Density: 1.532g/cm³
• Vapor Pressure: 3.52E-11mmHg at 25°C
• Refractive Index: 1.637
• CAS DataBase Reference: bis(4-nitrophenyl)peroxyanhydride(CAS DataBase Reference)
• NIST Chemistry Reference: bis(4-nitrophenyl)peroxyanhydride(1712-84-1)
• EPA Substance Registry System: bis(4-nitrophenyl)peroxyanhydride(1712-84-1)

Safety Data

• Hazardous Substances Data: 1712-84-1(Hazardous Substances Data)

Upstream product

• 122-04-3 4-nitro-benzoyl chloride 
• 62-23-7 4-nitro-benzoic acid 
• 98-88-4 benzoyl chloride 
• 10364-96-2 N-(4-nitrobenzoyl)imidazole 

Downstream Products

• 62-23-7 4-nitro-benzoic acid 
• 943-39-5 4-nitroperbenzoic acid 
• 70990-11-3 5,5-dimethyl-3-morpholin-4-yl-2,2-bis-(4-nitro-benzoyloxy)-cyclohex-3-enone 
• 15519-73-0 2,2'-Dihydroxy-4,4'-dimethylbiphenyl 
• 129194-43-0 4-Nitro-benzoic acid 2-hydroxy-5-methyl-phenyl ester 
• 114640-74-3 N-p-nitrobenzoyloxy-N-methyl-2-(o-formyl-phenyl)ethylamine 
• 78380-91-3 2-Hydroxy-4,4-dimethyl-6-(4-nitrobenzoyloxy)-2,5-cyclohexadien-1-on 
• 78477-00-6 2-(4-Nitrobenzoyloxy)-3-cyclohexylamino-5,5-dimethyl-2-cyclohexen-1-on 
• 78477-05-1 2--6-hydroxy-4,4-dimethyl-2,5-cyclohexadien-1-on 
• 78102-80-4 4-(4-Nitrobenzoyloxy)-1-oxaspiro<5.5>undec-4-en-2,3-dion 
• 78380-98-0 2-Hydroxy-4-(4-nitrobenzoyloxy)-spiro<5.5>undeca-1,4-dien-3-on 
• 78102-69-9 4,4-Dimethyl-2,6-bis(4-nitrobenzoyloxy)-2,5-cyclohexadien-1-on 
• 122628-18-6 4-Nitro-benzoic acid 1-(2-ethoxycarbonyl-allyl)-2-oxo-1,2-dihydro-naphthalen-1-yl ester 
• 93329-00-1 2-p-nitrobenzoyloxy-1-naphthol 

Relevant articles and documents

Thermoinduced Free-Radical C-H Acyloxylation of Tertiary Enaminones: Catalyst-Free Synthesis of Acyloxyl Chromones and Enaminones

In this paper, the direct acyloxylation of the α-C(sp2)-H bond in tertiary β-enaminones is accomplished under catalyst-free conditions and ambient temperature by using aroyl peroxides as coupling partners. By means of a thermoinduced free-radical pathway, the present method enables facile and efficient synthesis of both acyloxylated chromones and enaminones.

Iron(iii)-catalyzed chelation assisted remote C-H bond oxygenation of 8-amidoquinolines

Iron catalyzed site selective and chelation assisted C-H functionalization in 8-amidoquinolines is achieved. The remote C5-benzoxylation with benzoyl peroxide produced a variety of potentially bioactive 8-arylcarboxamido-5-benzoyloxy quinoline derivatives. The efficiency of the reaction reflects from the wide substrate scope with electronic differentiation on carboxamide and acyl peroxide in addition to tolerance of halo-substitutions on either of the aryls. The reaction is additive, silver free and proceeds without the exclusion of air or moisture.

Bimetallic reductive elimination from dinuclear Pd(III) complexes

In 2009, we reported C-halogen reductive elimination reactions from dinuclear Pd(III) complexes and implicated dinuclear intermediates in Pd(OAc)2-catalyzed C-H oxidation chemistry. Herein, we report results of a thorough experimental and theor