172271-46-4

Basic information

• Product Name: (Z)-3,4-methylenedioxycinnamyl (E)-3-(3,4,5-trimethoxyphenyl)acrylate
• Synonyms: (Z)-3,4-methylenedioxycinnamyl (E)-3-(3,4,5-trimethoxyphenyl)acrylate
• CAS NO: 172271-46-4
• Molecular Weight: 398.412
• Mol File: 172271-46-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-3,4-methylenedioxycinnamyl (E)-3-(3,4,5-trimethoxyphenyl)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3,4-methylenedioxycinnamyl (E)-3-(3,4,5-trimethoxyphenyl)acrylate(172271-46-4)
• EPA Substance Registry System: (Z)-3,4-methylenedioxycinnamyl (E)-3-(3,4,5-trimethoxyphenyl)acrylate(172271-46-4)

Safety Data

• Hazardous Substances Data: 172271-46-4(Hazardous Substances Data)

Upstream product

• 20329-98-0 (E)-3,4,5-trimethoxy-cinnamic acid 
• 90359-53-8 (Z)-3-(1,3-benzodioxol-5-yl)prop-2-enol 
• 172271-45-3 (Z)-methyl 3-(1,3-benzodioxol-5-yl)prop-2-enoate 

Downstream Products

• 103844-22-0 1,3,3aβ,4β,9β,9aα-hexahydro-4α-hydroxy-6,7,8-trimethoxy-9α-(3,4-methylenedioxyphenyl)naphtho<2,3-c>furan-3-one 
• 118826-03-2 1,3,9β,9aα-tetrahydro-6,7,8-trimethoxy-9α-(3,4-methylenedioxyphenyl)naphtho<2,3-c>furan-3-one 

Relevant articles and documents

A new synthesis of podophyllum lignans by Weitz' aminium salt-induced free radical cycloaddition reaction of a doubly unsaturated ester

(±)-Isopodophyllotoxin (1e) and related lactones 12, 13, 14 were synthesized by a biomimetic procedure from the doubly unsaturated esters 11a and 11b by means of an oxidative free radical cycloaddition reaction utilizing a stable cation radical salt, Weitz' aminium salt, in one step. (±)-Isopicropodophyllin (1g), the trans-fused lactones, 12, 13, and 16, and the cis-fused lactone 17 were also synthesized from the esters 11c and 11d by the reaction with the same reagent.