17284-66-1

Basic information

• Product Name: Dimethyl 3-methoxy-5-methylphthalate
• CAS NO: 17284-66-1
• Molecular Weight: 238.24
• Mol File: 17284-66-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Dimethyl 3-methoxy-5-methylphthalate(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl 3-methoxy-5-methylphthalate(17284-66-1)
• EPA Substance Registry System: Dimethyl 3-methoxy-5-methylphthalate(17284-66-1)

Safety Data

• Hazardous Substances Data: 17284-66-1(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 81722-05-6 3-methoxy-5-methyl-phthalic acid 
• 2161-93-5 1-methoxy-3-methyl-1,3-cyclohexadiene 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 851056-55-8 tri-O-methyl endocrocin 
• 6414-42-2 1,3,8-trimethoxy-6-methyl-9,10-anthraquinone 
• 100-84-5 1-methoxy-3-methyl-benzene 
• 13697-84-2 1-methoxy-5-methyl-cyclohexa-1,4-diene 
• 67116-21-6 6-methoxy-4-methyl-2H-pyran-2-one 

Downstream Products

• 81722-05-6 3-methoxy-5-methyl-phthalic acid 

Relevant articles and documents

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Syntheses of Highly Substituted Benzenes via Diels-Alder Reactions with 2H-Pyran-2-ones

The 2H-pyran-2-ones (α-pyrones) 1 react as dienes in Diels-Alder reactions with acetylene derivatives.The primarely formed cycloadducts immediately aromatize to benzenes by CO2 elimination.Thus, methyl acetylenedicarboxylate (2a) gives dimethyl phthalates 3, and methyl acetylenediphosphonate (2b) gives dimethyl 1,2-phenylenediphosphonates 8.The reactions of 1-(dimethylamino)-1-methoxyethene (9) with 1 regioselectively produce N,N-dimethylanilines 10 and isomeric homophthalate derivatives 12.Naphthoquinones 14 could be generated from 1,4-benzoquinone (13) and 1 in the presence of acetic anhydride and Pd/C.Hydroxy-2H-pyran-2-ones 4 react via their trimethylsilyl ether 6 analogously with 2a to give dimethyl (trimethylsiloxy)phthalates 7 which are easily converted to phenols 5 by acid-catalyzed hydrolysis.

Structure of diospyrin

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