174504-82-6Relevant articles and documents
A novel water-soluble tetranuclear copper (II) Schiff base cluster bridged by 2, 6-bis-[(2-hydroxyethylimino)methyl]-4-methylphenol in interaction with BSA: Synthesis, X-ray crystallography, docking and cytotoxicity studies
Asadi, Zahra,Golchin, Maryam,Eigner, Vaclav,Dusek, Michal,Amirghofran, Zahra
, p. 93 - 104 (2018)
A water-soluble tetranuclear copper (II) Schiff base complex bridged by 2,6-bis-[(2-hydroxyethylimino)methyl]-4-methylphenol, namely [Cu4(L1)2(O)(OAc)4].2H2O was synthesized. The complex was character
Tyrosinase and catecholase-like activities of a dinuclear Cu(II) complex
Chatterjee, Arnab,Yadav, Hare Ram,Choudhury, Angshuman Roy,Ali, Anzar,Singh, Yogesh,Ghosh, Rajarshi
, p. 140 - 146 (2017/12/26)
A dinuclear Cu(II) complex was synthesized and crystallographically characterized. The compound was found to have antiferromagnetic interaction in between the Cu(II) centres in the molecule. It had weak intermolecular ferromagnetic interaction. The compound was found to be tyrosinase and catecholase active. In case of tyrosinase activity, the diphenol formed was isolated using thin layer chromatography (TLC) and characterized through 1H NMR as well as mass spectrometry. The o-quinone derivative formed in this reaction was characterized using GC–MS. The latter activity was monitored spectrophotometrically and the product o-quinone derivative was isolated (in MeOH and MeCN) column chromatographically and characterized using melting point determination. These were followed by Michealis–Menten kinetics with turnover numbers 4.95 × 103 and 1.58 × 103 h?1 in MeOH and MeCN, respectively.
Synthesis, characterization and catalytic properties of multinuclear copper(II) complexes
Halder, Shibashis,Dey, Sudipto,Rizzoli, Corrado,Roy, Partha
, p. 85 - 93 (2014/06/09)
Four tetranuclear [Cu4(O)(Ln)2(CH 3COO)4] (1, 2, 4 and 5) and one pentanuclear [Cu 5(OH)2(L3)2(CH3COO) 6] (3) with N2O-dono
