176034-11-0

Basic information

• Product Name: Benzenamine, 3-(2-naphthalenyl)-
• CAS NO: 176034-11-0
• Molecular Formula: C16H13N
• Molecular Weight: 219.286
• Mol File: 176034-11-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenamine, 3-(2-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 3-(2-naphthalenyl)-(176034-11-0)
• EPA Substance Registry System: Benzenamine, 3-(2-naphthalenyl)-(176034-11-0)

Safety Data

• Hazardous Substances Data: 176034-11-0(Hazardous Substances Data)

Upstream product

• 16519-26-9 diethyl naphthalen-2-yl phosphate 
• 30418-59-8 3-Aminophenylboronic acid 
• 667940-23-0 2-(3-bromophenyl)naphthalene 
• 580-13-2 2-bromonaphthalene 
• 94064-82-1 2‐(3‐nitrophenyl)naphthalene 
• 13331-27-6 m-nitrobenzene boronic acid 
• 32316-92-0 naphthalene-2-boronic acid 
• 591-19-5 m-Bromoaniline 

Relevant articles and documents

Rapid heteroatom transfer to arylmetals utilizing multifunctional reagent scaffolds

Arylmetals are highly valuable carbon nucleophiles that are readily and inexpensively prepared from aryl halides or arenes and widely used on both laboratory and industrial scales to react directly with a wide range of electrophiles. Although C-C bond formation has been a staple of organic synthesis, the direct transfer of primary amino (-NH2) and hydroxyl (-OH) groups to arylmetals in a scalable and environmentally friendly fashion remains a formidable synthetic challenge because of the absence of suitable heteroatom-transfer reagents. Here, we demonstrate the use of bench-stable N-H and N-alkyl oxaziridines derived from readily available terpenoid scaffolds as efficient multifunctional reagents for the direct primary amination and hydroxylation of structurally diverse aryl- and heteroarylmetals. This practical and scalable method provides one-step synthetic access to primary anilines and phenols at low temperature and avoids the use of transition-metal catalysts, ligands and additives, nitrogen-protecting groups, excess reagents and harsh workup conditions.

Organic electroluminescent compound, organic electroluminescent device and application thereof

The invention relates to the field of luminescent materials and particularly provides an organic electroluminescent compound, an organic electroluminescent device and application thereof. A structural formula of the organic electroluminescent compound is as shown below in the description. The compound can serve as HTL, EBL, B-dopant, Host, EBL, ETL and CPL materials. When used in the organic electroluminescent device, the organic electroluminescent compound can reduce driving voltage, improve luminescent efficiency, brightness, heat stability, color purity and prolong the service life of the device.

Nickel-catalyzed cross-coupling of aryl phosphates with arylboronic acids

The Suzuki-Miyaura cross-coupling of aryl phosphates using Ni(PCy 3)2Cl2 as an inexpensive, bench-stable catalyst is described. Broad substrate scope and high efficiency are demonstrated by the syntheses of more than 40 biaryls and by constructing complex organic molecules. The poor reactivity of aryl phosphates relative to aryl halides is successfully employed to construct polyarenes by selective cross-coupling using Pd and Ni catalysts.